| Title: |
Coating of aluminum powder with polymers in supercritical
carbon dioxide
|
| Author: | |
| Document Type: |
Thesis
|
| Department: |
Department of Chemical Engineering, Chemistry and Environmental
Science
|
| Degree: |
Master of Science
|
| Major: |
Applied Chemistry
|
| Advisory Committee: |
Krasnoperov, Lev N.
Bozzelli, Joseph W.
Pfeffer, Robert
|
| Thesis Date: |
2001, May
|
| Keywords: |
Aluminum powder
Polymers
Supercritical carbon dioxide
|
| Availability: |
Unrestricted
|
| Abstract: |
Eleven polymers were used to produce coatings (2-20 nm) on the surface of an aluminum powder to modify its properties. The polymers studied are polyisobutylene (PIB), poly (vinylidene fluoride) (PVF), poly (methyl methacrylate) (PMMA), polystyrene (PS), poly(ethylene terephthalate) (PETP), poly(4-vinylbiphenyl) (PVB), poly(4-vinylpyridine) (PVP), poly(4-bromo styrene) (PBS), poly (vinylidene fluorideco-hexafluoropropylene) (PVFH), poly (styrene-co-methyl methacrylate) (PSMMA), poly (vinyl chloride-co-vinyl acetate) (PVCVA). Supercritical carbon dioxide was used as a solvent and as a transport medium. Coated aluminum powders exhibit enhanced resistance to the dissolution in basic solutions. The protective properties of the polymeric films were quantified based on the dissolution rate. Polymeric films that contain aromatic rings were characterized using UV absorption spectrophotometry. Temperature and pressure were varied over 84 - 210 OC and 80 -480 atm to determine the optimal condition for coating. A technique to measure the solubilities of poorly soluble polymers in supercritical carbon dioxide was developed. The solubility of PVB is determined as 11.7 mg/L at T = 170°C and p = 341 atm. The study of the morphology of the coated powder was carried on by using an Environmental Scanning Electron Microscope (ESEM) and an Electron-Dispersive Xray Detector (EDX). The coatings produced using supercritical carbon dioxide as well as using organic solvents were compared and evaluated. |
| Complete Thesis: |
njit-etd2001-030
(85 pages ~ 3,349 KB pdf)
|
| Feedback: |
Please complete this Feedback Form to inform us about your experience using this website. It will
assist us in better serving your information needs in the future. Thank
You!
|
|
Created December 5, 2002
To view these documents you will need the Acrobat Reader Plug-in. If you do not have it you can download it free from
|