| Title: | Analysis of the oxidation of isotox by immobilized bacteria |
| Author: | |
| Document Type: | Thesis |
| Department: | Department of Chemical Engineering, Chemistry and Environmental Science |
| Degree: | Master of Science |
| Major: | Environmental Science |
| Advisory Committee: |
Sofer, Samir S.
Trattner, Richard B.
Knox, Dana E.
|
| Thesis Date: | 1995, May |
| Keywords: |
Pesticides--Biodegradation.
Immobilized microorganisms.
|
| Availability: | Unrestricted |
| Abstract: |
The purpose of this work is to show the effects of bio-oxidation of a pesticide through a spiral wound bioreactor using immobilized mixed culture bacteria. The pesticide used for this study is Isotox® and its active ingredients are acephate or O,S-dimethyl acetylphosphoramidothioate and vendex or hexakis (2-methyl-2-phenylpropyI)- distannoxane. Qualitative analysis of the product indicated presence of sulfate. A consistent and unique DO pattern for Isotox® showed at least 4 minima, whereas phenol has only one minimum. The consistency of the DO pattern for Isotox® has been observed for over 30 injections into the bioreactor system. For both an acclimated and an unacclimated system, the basic DO pattern was consistent. The analysis of bio-oxidized reservoir water showed concentrations in the ranges of parts per billion (ppb). About 90% of the vendex injected was adsorbed by the bacteria as indicated by tin analysis of the product water. A single batch of 16.4784 g dry biomass immobilized on a spiral bioreactor was able to effectively remove 2338 ml of the pesticide containing over 1000 ppm tin. Adsorption is on the order of 0.086 g tin per gram dry bacteria. |
| Complete Thesis: | njit-etd1995-035 (70 pages ~ 2,310 KB pdf) |
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Created August 22, 2012
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