Two models for the extraction of phenol by means of liquid surfactant membranes is presented in which external mass transfer around w/o emulsion drop, phase and chemical equilibria are taken into account.

The nonlinear coupled P.D.E.'s is solved under assumptions to get a close-formed analytical approximate solution. The experimental results on the batch extraction of phenol are found to be satisfactory simulated by one of the proposed models provided that phenol concentration is higher than 0.01N. The model requires no adjustable parameter thus it can predict the extraction behavior without doing experiments.