| Title: | Absolute viscosity of the n-paraffin liquids |
| Author: | |
| Document Type: | Thesis |
| Department: | Department of Chemical Engineering |
| Degree: | Master of Science |
| Major: | Chemical Engineering |
| Advisory Committee: |
Kreps, Saul I.
Mantell, C. L.
Keeffe, George C.
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| Thesis Date: | 1960 |
| Keywords: |
Paraffins
Viscosity
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| Availability: | Unrestricted |
| Abstract: |
The absolute viscosity of the normal paraffins C5H12 to C20H42 was studied to determine a relationship more useful in predicting liquid viscosities than existing correlations such as the methods of Andrade, Souders, Thomas, and Doolittle. It was found that a function of corresponding liquid states could be designed which related viscosity to the number of carbon atoms. This function, here called liquidity, is defined as the extent to which a substance exists as a liquid with respect to temperature. This function can be expressed mathematically as: Lc = (t - tm)/(tc - tm) or Lb = (t-tm)/(tb-tm); where: Once the basis for liquidity is determined, the denominator in the above expressions remain constant, and the % liquidity becomes a straight line function of the temperature. It was further found that a plot of Lc vs. number of carbon atoms for the n - paraffins resulted in curves of iso - viscosity which, when fitted to straight lines, could be used for calculation, extrapolation, or interpolation of viscosity data. Thus, a method was developed for the viscosity prediction of the n - paraffins above C4H10 to apply at any temperature within the normal liquid range. Deviations from the experimental values of viscosity to those resulting from the designed liquidity function are within ± 10 per cent for the majority, and less than ± 20 per cent for the extreme cases. This approach to viscosity prediction is valid with or without the availability of experimental data. |
| Complete Thesis: | njit-etd1960-001
(51 pages ~ 3,955 KB pdf)
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