NJIT eTD: The New Jersey Institute of Technology's electronic Theses & Dissertations
Title:
Absolute viscosity of the n-paraffin liquids
Author:
Permutt, Gerald
Document Type:
Thesis
Department:
Department of Chemical Engineering
Degree:
Master of Science
Major:
Chemical Engineering
Advisory Committee:
Kreps, Saul I.
Mantell, C. L.
Keeffe, George C.
Thesis Date:
1960
Keywords:
Paraffins
Viscosity
Availability:
Unrestricted
Abstract:

The absolute viscosity of the normal paraffins C5H12 to C20H42 was studied to determine a relationship more useful in predicting liquid viscosities than existing correlations such as the methods of Andrade, Souders, Thomas, and Doolittle.

It was found that a function of corresponding liquid states could be designed which related viscosity to the number of carbon atoms. This function, here called liquidity, is defined as the extent to which a substance exists as a liquid with respect to temperature. This function can be expressed mathematically as:

Lc = (t - tm)/(tc - tm) or Lb = (t-tm)/(tb-tm);

where:
Lc = liquidity based on the critical temperature
Lb = liquidit based on the normal boiling temperature
t = any temperature, °C
tb = normal boiling temperature, °C
tc = critical temperature, °C
tm = normal melting temperature, °C

Once the basis for liquidity is determined, the denominator in the above expressions remain constant, and the % liquidity becomes a straight line function of the temperature.

It was further found that a plot of Lc vs. number of carbon atoms for the n - paraffins resulted in curves of iso - viscosity which, when fitted to straight lines, could be used for calculation, extrapolation, or interpolation of viscosity data. Thus, a method was developed for the viscosity prediction of the n - paraffins above C4H10 to apply at any temperature within the normal liquid range. Deviations from the experimental values of viscosity to those resulting from the designed liquidity function are within ± 10 per cent for the majority, and less than ± 20 per cent for the extreme cases. This approach to viscosity prediction is valid with or without the availability of experimental data.

Complete Thesis:
njit-etd1960-001 (52 pages ~ 2,848 KB pdf)
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Created June 14, 2005
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